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Onions: sweet mostly.
Potatoes (not Russets, but a variety like Kennebec): savory, a little bitter
Rhubarb: sweet, sour
Cabbage: umami, bitter
Carrots: sweet, savory (depending on the variety)
Parsley: savory, bitter
Swiss Chard: savory, bitter
Beets: umami, bitter, sweet (depending on the variety)
It's really hard to lump some flavors into the five categories (though I know them) because they are more nuanced, especially the aromatics like garlic and onions.