An exceedingly generous Uruguayan guy gave me step-by-step instructions on how to do it, as he does it all the time for exactly the same reason - to end his reliance on Ferro Frits.
His instructions were to slowly take the colemanite up to 680C and hold it there until the heat coming out of the top hole in the kiln stops steaming up a glass or mirror.
I followed his instructions, but was interested to see if the colemanite gave off its water at the temp #AI suggested.